Critical Point Definition

What Is the Critical Point in Chemistry?

This is a phase diagram, which includes the critical point and triple point.
This is a phase diagram, which includes the critical point and triple point. Booyabazooka, Wikipedia Commons

Critical Point Definition

In a phase diagram, the critical point or critical state is the point at which two phases of a substance initially become indistinguishable from one another. The critical point is the end point of a phase equilibrium curve, defined by a critical pressure Tp and critical temperature Pc. At this point, there is no phase boundary.

Also Known As: critical state

Critical Point Examples

The liquid-vapor critical point is the most common example, which is at the end point of the pressure-vapor temperature curve distinguishing a substance's liquid and vapor. The meniscus between steam and water vanishes at temperatures above 374°C and pressures above 217.6 atm, forming what is known as a supercritical fluid.

There is also a liquid-liquid critical point in mixtures, which occurs at the critical solution temperature.

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Helmenstine, Anne Marie, Ph.D. "Critical Point Definition." ThoughtCo, Sep. 29, 2022, thoughtco.com/definition-of-critical-point-605853. Helmenstine, Anne Marie, Ph.D. (2022, September 29). Critical Point Definition. Retrieved from https://www.thoughtco.com/definition-of-critical-point-605853 Helmenstine, Anne Marie, Ph.D. "Critical Point Definition." ThoughtCo. https://www.thoughtco.com/definition-of-critical-point-605853 (accessed April 24, 2024).